Prepare rice according to package directions. Cool.
In a medium bowl combine pudding mix with milk. Whisk until thickened. Fold in rice and topping. Refrigerate until set, about 1 hour.
Meanwhile, in a medium saucepan combine pecans and sugar. Stir occasionally over medium-low heat until sugar melts, coating all the pecans. Pour mixture out onto a sheet of parchment paper that had been coated with non-stick cooking spray. Allow to cool completely. Break into small pieces.
When pudding has cooled, spoon into serving dishes and top with pecan praline pieces.